Unsymmetrical, Cyclic Diborenes and Thermal Rearrangement to a Borylborylene
نویسندگان
چکیده
منابع مشابه
Synthesis of cyclic diborenes with unprecedented cis-configuration.
The first examples of cis-configured diborenes - and the first cyclic diborenes - are isolated by taking advantage of stabilisation by chelating diphosphine ligands. The diborenes are prepared by a convenient one-pot reductive procedure that circumvents the need for a pre-formed base-adduct of the boron-containing precursor.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2018
ISSN: 1433-7851
DOI: 10.1002/anie.201800671